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steroid 2223KbAbstractThe synthetic utility of (S) 2 (diphenylmethyl) pyrrolidine (1) and its amide derivative, (S) 2 (diphenylmethyl) 5 oxo pyrrolidine (2) were examined in two contexts; as chiral auxiliary compounds in asymmetric alkylation reactions and Diels Alder reactions; as chiral solvating agents (CSAs) for (^1)NMR evaluation of chiral acids and alcohols. In the former case, it was shown that monoalkylation of N acyl derivatives of (1) and (2) using lithiated bases led to poor diastereoselectivities (1:1 to 1.12:1) and poor yields (28 to 33 %), while alkylation reactions using HMPA proceeded with modest diastereoselectivities (1.49:1 to 4.25:1). The results of the Diels Alder study remain premature at present. steroid

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